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Nature does not make caffeine or any substance in mono-structured form, including caffeine. Caffeine consumed by itself is harmful (a la caffeine pills -- nature does not produce caffeine pills). Caffeine pills are INORGANIC and thus not absorbed by the body (the cells). Bio-caffeiene from plant sources is ORGANIC and thus absorbable. Organic substances can be absorbed through the cells. Inorganic substances cannot. Inorganic caffeine blocks reuptake of glutamate, and that's another reason why synthetic caffeine is harmful. Organic caffeine does not block reuptake of glutamate.
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